Angewandte Chemie International Edition in English · 1963 · 29 citations · 3 references
Natural SciencesChemistryCatalysisGreen ChemistryOrganic ChemistryHeterocyclic ChemistryOrganic SynthesisBackbone Cleavage MechanismsCleavage
Abstract Dihydroxydiarylmethane derivatives are formed by condensation of aromatic hydroxy and carbonyl compounds in the presence of acidic condensing agents at low temperatures or in the presence of bases at elevated temperatures. This article deals with formation and cleavage mechanisms in acid and basic media. As a result of the investigations reported, new methods of preparing unsymmetric dihydroxydiarylmethane derivatives and p‐alkenylphenols have been developed.
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