Pd-catalyzed cross-coupling reactions of halogenated 1-phenylpyrazol-3-ols and related triflates

A convenient synthesis of acetylenes: catalytic substitutions of acetylenic hydrogen with bromoalkenes, iodoarenes and bromopyridines

Kenkichi Sonogashira, Yasuo Tohda, Nobue Hagihara · Tetrahedron Letters · 1975 · 5.1K citations

Chemical Engineering, Catalytic Substitutions, Engineering +8

The Palladium‐Catalyzed Cross‐Coupling Reactions of Organotin Reagents with Organic Electrophiles [New Synthetic Methods (58)]

J. K. Stille · Angewandte Chemie International Edition in English · 1986 · 3.4K citations

Cross-coupling Reaction, Engineering, Natural Sciences +10

Stereoselective synthesis of arylated (E)-alkenes by the reaction of alk-1-enylboranes with aryl halides in the presence of palladium catalyst

Norio Miyaura, Akira Suzuki · Journal of the Chemical Society Chemical Communications · 1979 · 1.1K citations

High Yields, Aryl Halides, Cross-coupling Reaction +10

Acylation, methylation, and carboxyalkylation of olefins by Group VIII metal derivatives

Richard F. Heck · Journal of the American Chemical Society · 1968 · 774 citations

Derivative (Chemistry), Molecular Sciences, Derivatives +14

Pyrazole Ligands:  Structure−Affinity/Activity Relationships and Estrogen Receptor-α-Selective Agonists

Shaun R. Stauffer, Christopher J. Coletta, Rosanna Tedesco et al. · Journal of Medicinal Chemistry · 2000 · 757 citations

Molecular Pharmacology, Biochemistry, Functional Selectivity +12