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Indirect Electrooxidation of Alcohols by a Double Mediatory System with [R<sub>2</sub>N<sup>+</sup>= O]/R<sub>2</sub>N-O . and [Br. or Br<sup>+</sup>]Br<sup>-</sup>Redoxes
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1990
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Double Mediatory SystemChemical EngineeringEngineeringIndirect ElectrooxidationActive Bromine SpeciesBioelectrochemistryElectrosynthesisOrganic ChemistryBromide IonCatalysisRedox ChemistryChemistryRedox BiologyElectrochemistry
A double mediatory system consisting of N-oxoammonium salts and active bromine species, generated from 2,2,6,6-tetramethylpiperidine-1-oxyl derivatives and bromide ion as recyclable reagents, is useful for the selective electrooxidation of primary and secondary alcohols to aldehydes and ketones, respectively, in an aqueous-organic two-phase system.