Concepedia

Rhodium-catalysed arylation of aldehydes with arylstannanes

Shuichi Ôi, Mitsutoshi Moro, Yoshio Inoue

Chemical Communications · 1997 · 50 citations · 11 references

DOI

Concepts

Abstract

Aryltrimethylstannanes react with aldehydes in the presence of a catalytic amount of a cationic rhodium complex, [Rh(cod)(MeCN) 2 ]BF 4 , affording the corresponding arylated secondary alcohols in good yields.

References

11

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Catalytic effect of nickel(II) chloride and palladium(II) acetate on chromium(II)-mediated coupling reaction of iodo olefins with aldehydes

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Grignard-type carbonyl addition of allyl halides by means of chromous salt. A chemospecific synthesis of homoallyl alcohols

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Reactions of alkenylchromium reagents prepared from alkenyl trifluoromethanesulfonates (triflates) with chromium(II) chloride under nickel catalysis

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