Microscopy and Spectroscopy of Lithium Nickel Oxide-Based Particles Used in High Power Lithium-Ion Cells

Abstract

Structural and electronic investigations were conducted on lithium nickel oxide-based particles used in positive electrodes of 18650-type high-power Li-ion cells. K-edge X-ray absorption spectroscopy (XAS) revealed trivalent Ni and Co ions in the bulk powder used to prepare the high power electrode laminates. Using oxygen K-edge XAS, high resolution electron microscopy, nanoprobe diffraction, and electron energy-loss spectroscopy, we identified a thick modified layer on the surface of the oxide particles, which results from the loss of Ni and Li ordering in the layered structure. This structural change was accompanied by oxygen loss and a lowering of the Ni- and Co-oxidation states in the surface layer. Growth of this surface layer may contribute to the impedance rise observed during accelerated aging of these Li-ion cells. © 2003 The Electrochemical Society. All rights reserved.