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The mechanism of oxidation of alkanes by peroxo complexes of iron porphyrins in the presence of acylating agents: a model for activation of O2 by cytochrome P-450
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1984
Year
Advanced Oxidation ProcessEngineeringOrganic ChemistryChemistryRedox BiologyOxidative StressAdvanced Oxidation ProcessesIron PorphyrinsCytochrome P-450 OxidationRedox ChemistryBiochemistryPhotochemistryRadical (Chemistry)Cytochrome P-450SpectroelectrochemistryReactive Oxygen SpeciePeroxo ComplexesO2 ActivationMedicineChemical KineticsDeoxygenationCarbonyl Metabolism
A new model for cytochrome P-450 oxidation of alkanes, which imitates the process of O2 activation by cytochrome P-450, involving the formation of iron porphyrin peroxo complexes in the presence of acylating agents is proposed.