Publication | Closed Access
Highly enantioselective hydroaminoalkylation of secondary amines catalyzed by group 5 metal amides with chiral biarylamidate ligands
106
Citations
28
References
2010
Year
Chiral AminesAsymmetric CatalysisChemical EngineeringCross-coupling ReactionEngineeringNovel OrganocatalystsChiral Biarylamidate LigandsOrganic ChemistryMetal AmidesCatalysisStereoselective SynthesisChemistryEnantioselective Group 5Secondary AminesGroup 5Organometallic CatalysisEnantioselective SynthesisBiomolecular Engineering
A highly enantioselective group 5 metal amide catalyst system is reported for the hydroaminoalkylation of secondary amines to give chiral amines in good yields with excellent ee values (up to 93%) by loading of 5% precatalyst.
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