Concepedia

Catalytic Transformation of Cyclohexene Hydroperoxides to Epoxy Alcohols with Vanadyl Acetylacetonate

Takashi Itoh, Kiyotomi Kaneda, Shiichirō Teranishi

Bulletin of the Chemical Society of Japan · 1975 · 10 citations · 3 references

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Concepts

Abstract

Abstract Cyclohexene hydroperoxide and its methyl derivatives undergo rearrangement in the presence of the vanadyl acetylacetonate catalyst to the corresponding epoxyalcohols with high cis-stereoselectivity in high yields.

References

3

High stereo- and regioselectivities in the transition metal catalyzed epoxidations of olefinic alcohols by tert-butyl hydroperoxide

K. Barry Sharpless, Robert Michaelson · Journal of the American Chemical Society · 1973 · 739 citations

, , +8

Metal-catalyzed epoxidation of olefins with organic hydroperoxides I. A comparison of various metal catalysts

Roger A. Sheldon · Journal of Catalysis · 1973 · 268 citations

, , +15

Iodometric Determination of Peroxygen in Organic Compounds

Vaman R. Kokatnur, Murray Jelling · Journal of the American Chemical Society · 1941 · 154 citations

, , +7