The Journal of Chemical Physics · 1952 · 22 citations · 8 references
Natural SciencesPhysicsQuantum MechanicsPartition CoefficientStatistical MechanicsPartition FunctionQuantum Mechanical ModelQuantum Partition FunctionQuantum Virial ExpansionVirial CoefficientsVirial ExpansionVirial Theorem
An exact evaluation is attempted of the quantum-mechanical partition function for an assembly of similar particles with central interaction. Quantum-mechanical analogs of the classical cluster integrals are derived and evaluated as far as required to determine the virial coefficients. It is shown that the results are particularly well adapted for computation at very low temperatures.
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On the Quantum Correction For Thermodynamic Equilibrium
E. P. Wigner · Physical Review · 1932 · 9.2K citations