Journal of the Chemical Society A Inorganic Physical Theoretical · 1970 · 53 citations · 0 references
Natural SciencesChemistryChemical KineticsInorganic ChemistryOrganic ChemistryAcid-base ChemistryCarbonyl ChemistryCarbonyl ComplexesCoordination ChemistryAcid-base ReactionsComplexation ChemistryIntrinsic Kinetic Isotope EffectPolynuclear ComplexesProtonation EffectsSolvent Kinetic Isotope Effect
The protonation of some polynuclear carbonyl complexes in concentrated sulphuric acid has been studied and the new complexes [HRu3(CO)12]PF6 and [HOs3(CO)12]PF6 have been isolated. The kinetic isotope effect observed in these protonation reactions has been investigated and the new complex HOsCo3(CO)12 has been prepared.