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A Monomeric, Donor-free Lithium Complex with a New Overcrowded β-Diketiminato Ligand
13
Citations
7
References
2004
Year
Materials ScienceInorganic ChemistryEngineeringCoordination ComplexUnique StructureDonor-coordinated Lithium β-DiketiminatesMolecular ComplexX-ray Structural AnalysisChemistryCrystallographyCrystal Structure DesignInorganic SynthesisBiomolecular EngineeringDonor-free Lithium Complex
Abstract A monomeric, donor-free complex of lithium with a new overcrowded β-diketiminato ligand, [Li{TbtNC(Me)CHC(Me)NMes}] (Tbt = 2,4,6-[CH(SiMe3)2]3C6H2, Mes = mesityl), was synthesized and isolated as colorless crystals. Its unique structure was revealed by X-ray structural analysis to be compared with those of donor-coordinated lithium β-diketiminates.
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