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Bis(η<sup>6</sup>-toluene)thallium(I) 7,8,9,10,11,12-Hexabromo-<i>closo</i>-1-carbadodecaborate: a Halocarborane-Bridged Dimer with Heavy Metal–Arene Interactions
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1997
Year
Materials ScienceInorganic ChemistryEngineeringHeterocyclicη6 InteractionsCoordination ComplexHalocarborane-bridged DimerOrganometallic CatalysisMain Group ChemistryMolecular ComplexChemistryTitle CompoundHeterocycle ChemistryPharmacologyToluene MoleculesDerivative (Chemistry)
The title compound, [Tl(C7H8)2](CB11H6Br6), shows Tl+ having η6 interactions with two toluene molecules and dative interactions with two Br atoms of one carborane anion and one Br atom of a neighboring anion.