Concepedia

Promising Material for Infrared Nonlinear Optics: NaI<sub>3</sub>O<sub>8</sub> Salt Containing an Octaoxotriiodate(V) Anion Formed from Condensation of [IO<sub>3</sub>]<sup>−</sup> Ions

Delphine Phanon, Isabelle Gautier‐Luneau

Angewandte Chemie International Edition · 2007 · 230 citations · 30 references

DOI

Concepts

Abstract

Off-center: The material NaI3O8 is obtained as millimeter-sized single crystals (see photograph of a single crystal; crystal size: 2×2×5 mm3), and its crystal structure is acentric. It is transparent up to 12.5 μm, thus covering the three atmospheric transparency windows. It generates an intense second-harmonic-generation signal and has a high optical damage threshold.

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