Electrochemistry of P450cin: new insights into P450 electron transfer

Kondo‐François Aguey‐Zinsou, Paul V. Bernhardt, James J. De Voss, Kate E. Slessor

Chemical Communications · 2003 · 49 citations · 17 references

Concepts

Abstract

Electrochemistry of bacterial cytochrome P450cin (CYP176A) reveals that, unusually, substrate binding does not affect the heme redox potential, although a marked pH dependence is consistent with a coupled single electron/single proton transfer reaction in the range 6 < pH < 10.

References

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