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Five‐coordinate Tervalent Phosphorus in the Tricyanobromo‐ and ‐iodophosphate(<scp>III</scp>) Ion
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1979
Year
Inorganic ChemistryEngineeringBiochemistryFirst PhosphorusNatural SciencesCoordination ComplexFive‐coordinate Tervalent PhosphorusOrganic ChemistryMain Group ChemistryPseudo-octachedral Lignad GeometryChemistryCrystallographyInorganic SynthesisCoordination Number 5Inorganic Compound
The first phosphorus(III) compounds found to have coordination number 5 are the crown ether-alkali metal salts NaP(CN)3X, X = Br, I. A pseudo-octachedral lignad geometry is attained by dimerization of the anion.
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