Organic Letters · 2010 · 62 citations · 18 references
Natural SciencesChemical EngineeringChemistryElectrochemical EngineeringElectrochemistryReaction EngineeringElectrochemical CellsElectrochemical SynthesisElectrode-electrolyte InterfacesElectrolysis ProcessesOxidation-reduction ReactionsCurrent DensityElectrochemical ConversionElectrochemical OxidationElectrochemical Reaction MechanismsElectrochemical Reduction
The electrochemical reduction of diphenylphosphinate esters leads smoothly and in high yields to the corresponding deoxygenated products. In comparison with the previously developed methodologies, the electrolysis could be performed at lower temperature and with a higher current density, resulting in a shorter reaction time.
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Modern methods for the radical deoxygenation of alcohols
Wolfgang Hartwig · Tetrahedron · 1983 · 321 citations