Concepedia

First tether-directed regioselective bis-functionalisation of C70: effects of cation complexation on the redox properties of diastereoisomeric fullerene crown ether conjugates

Maurice J. van Eis, Paul Seiler, François Diederich, Robert J. Alvarado, Luis Echegoyen

Chemical Communications · 2000 · 28 citations · 17 references

DOI

Concepts

Abstract

The covalently templated bis-functionalisation of C70, employing a dibenzo-18-crown-6 tether, proceeds with complete regiospecificity and provides a bis-addition pattern which is disfavoured in sequential transformations.

References

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Templated Regioselective and Stereoselective Synthesis in Fullerene Chemistry

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(.eta.2-C70)Ir(CO)Cl(PPh3)2: the synthesis and structure of an iridium organometallic derivative of a higher fullerene

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Tether‐Directed Remote Functionalization of Buckminsterfullerene: Regiospecific Hexaadduct Formation

Lyle Isaacs, Richard F. Haldimann, François Diederich · Angewandte Chemie International Edition in English · 1994 · 213 citations

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Rationalization of the unusual electrochemical behavior observed in lariat ethers and other reducible macrocyclic systems

S.R. Miller, Deborah A. Gustowski, Zhi Hong Chen et al. · Analytical Chemistry · 1988 · 192 citations

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