Concepedia

A unique Bi–Bi bond forming reaction using organobismuth oxides and phosphorus compounds bearing a P(O)H group

Shigeru Shimada, Junpei Maruyama, Yoong‐Kee Choe, Takashi Yamashita

Chemical Communications · 2009 · 36 citations · 28 references

DOI

Concepts

Abstract

A new dibismuthane bearing a 5,6,7,12-tetrahydrodibenz[c,f][1,5]azabismocine framework was obtained in high yield by a unique reaction of the corresponding organobismuth oxide and organophosphorus compounds with a P(=O)H group.

References

28

Efficient Fixation of Carbon Dioxide by Hypervalent Organobismuth Oxide, Hydroxide, and Alkoxide

Shuang‐Feng Yin, Junpei Maruyama, Takashi Yamashita et al. · Angewandte Chemie International Edition · 2008 · 115 citations

, , +11

5,6,7,12‐Tetrahydrodibenz[<i>c,f</i>][1,5]azabismocines: Highly Reactive and Recoverable Organobismuth Reagents for Cross‐Coupling Reactions with Aryl Bromides

Shigeru Shimada, Osamu Yamazaki, Toshifumi Tanaka et al. · Angewandte Chemie International Edition · 2003 · 90 citations

, , +1

Organometallic compounds with SbSb or BiBi bonds

H.J. Breunig · Coordination Chemistry Reviews · 2004 · 89 citations

, , +8

Isomers of a Dibismuthane, R<sub>2</sub>Bi−BiR<sub>2</sub> [R = 2,6-(Me<sub>2</sub>NCH<sub>2</sub>)<sub>2</sub>C<sub>6</sub>H<sub>3</sub>], and Unusual Reactions with Oxygen:  Formation of [R<sub>2</sub>Bi]<sub>2</sub>(O<sub>2</sub>) and R‘R‘ ‘Bi [R‘ = 2-(Me<sub>2</sub>NCH<sub>2</sub>)-6-{Me<sub>2</sub>N(O)CH<sub>2</sub>}C<sub>6</sub>H<sub>3</sub>; R‘ ‘ = 2-(Me<sub>2</sub>NCH<sub>2</sub>)-6-{O(O)C}C<sub>6</sub>H<sub>3</sub>]

Lucia Balázs, H.J. Breunig, Enno Lork et al. · Inorganic Chemistry · 2006 · 86 citations

, , +13

Synthesis and chemical behaviors of 12-substituted dibenz[c,f][1,5]azastibocine and dibenz[c,f][1,5]azabismocine derivatives: evidences of 10-Pn-4 type hypervalent interaction

Katsuo Ohkata, Shin Takemoto, Masako Ohnishi et al. · Tetrahedron Letters · 1989 · 74 citations

, , +8