Journal of Forensic Sciences · 2005 · 45 citations · 7 references
PharmacyToxicologyDiagnostic ToxicologyForensic Pharmaceutical AnalysisForensic ToxicologyBioterrorism DetectionChemical TerrorismDiagnostic Test DesignExplosives AnalysisExplosives DetectionFalse Positive MeasurementFalse-positive ResultsPigment IdentificationTerrorist Attack
A sensitive, specific and simple color test for the improvised explosive urea nitrate is described. It is based on the formation of a red pigment upon the reaction between urea nitrate and p-dimethylaminocinnamaldehyde (p-DMAC) under neutral conditions. Urea itself, which is the starting material for urea nitrate, does not react with p-DMAC under the same conditions. Other potential sources of false positive response e.g., common fertilizers, medications containing the urea moiety and various amines, do not produce the red pigment with p-DMAC. Exhibits collected from 10 terrorist cases have been tested with p-DMAC. The results were in full agreement with those obtained by instrumental techniques including GC/MS, XRD and IR.
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The crystal structure of urea nitrate
Sybolt Harkema, D. Feil · Acta Crystallographica Section B · 1969 · 43 citations · Full text