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Dynamic Proton Polarization in Butanol Water Below 1 K
25
Citations
5
References
1969
Year
EngineeringPhysicsLargest PolarizationNatural SciencesProton TransferComparable PolarizationPolar EnvironmentsHydrogen-bonded LiquidDynamic Nuclear PolarizationPhysical ChemistryHydrogenChemistryPolarization ImagingChemical KineticsDynamic Proton Polarization
We have measured the temperature dependence of the dynamic proton polarization in a 0.2-g sample of 95% 1-butanol and 5% water, containing 0.75% of the free radical porphyrexide, between 1.4 and 0.5 K. The largest polarization attained was 67% at 0.5 K. The feasibility of achieving comparable polarization in larger samples and the question of the origin of the observed temperature dependence are discussed.
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