Mass Spectrometric Identification of Aldonolactones as Trimethylsilyl Ethers.

Göran Petersson, Olof Samuelson, K. Anjou, Erik von Sydow, G. Eriksson, R. Blinc, S. Paušak, L. Ehrenberg, J. Dumanović

Acta chemica Scandinavica/Acta chemica Scandinavica. B, Organic chemistry and biochemistry/Acta chemica Scandinavica. A, Physical and inorganic chemistry/Acta chemica Scandinavica. Series B. Organic chemistry and biochemistry/Acta chemica Scandinavica. Series A, Physical and inorganic chemistry · 1967 · 45 citations · 0 references

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Abstract

Trimethylsilyl ethers of aldonolactones are useful for the identification of aldonic acids by mass spectrometry. Peaks recorded for the molecular ion (M) and for mass M-15 give a reliable determination of the molecular weight. Significant differences exist between 1,4- and 1,5-lactones. All diastereomers studied can be well distinguished from each other.