Chemical Communications · 2002 · 44 citations · 6 references
Natural SciencesChemistryMaterials ScienceCrystal StructureInorganic ChemistryNanomaterialsCluster ChemistryCluster CompoundsCoordination ChemistryCrystal ChemistryMolecular StructureTransition Metal ComplexesCluster GeometryCluster ReactivityCluster SynthesisLigand-stabilized ClustersMetal-sulfur ClustersNoble Metal ClustersStructural Characterization Of ClustersTransition Metal Clusters
A silver 4-tert-butylthiophenolate complex generated in situ reacted with CS2 in acetone to give an anionic cluster [Ag50S7(SC6H4But-4)40]4-, the core of which consists of fifty silver atoms and forty-seven sulfur atoms, shaped like a discus with a diameter of ca. 2.0 nm.
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Harald Krautscheid, Dieter Fenske, Gerhard Baum et al. · Angewandte Chemie International Edition in English · 1993 · 165 citations
Synthesis and crystal structure of a polymeric complex [S4Cd17(SPh)24(CH3OCS2)4/2]n·nCH3OH
Xianglin Jin, Kaluo Tang, Shaojuan Jia et al. · Polyhedron · 1996 · 36 citations