Concepedia

Reductive Addition of Alkyl Radical to Phenyl Vinyl Sulfone

Hideo Togo, Masahiko Aoki, Masataka Yokoyama

Chemistry Letters · 1992 · 20 citations · 19 references

DOI

Concepts

Abstract

Abstract Radicals generated from (diacyloxyiodo)benzene readily added to phenyl vinyl sulfone to give 2-alkylethyl phenyl sulfone in the presence of a hydrogen donor such as 1,4-cyclohexadiene, 1,3-dioxolane, or triethylsilane. Among these donors, 1,4-cyclohexadiene was the most effective.

References

19

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Iodosobenzene diacetate, an efficient reagent for the oxidative decarboxylation of carboxylic acids

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Invention of new reactions useful in the chemistry of natural products

Derek H. R. Barton, Samir Z. Zard · Pure and Applied Chemistry · 1986 · 148 citations · Full text

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Sequential alkoxy radical fragmentation - transannular radical cyclisation - radical ring expansion reactions. A new approach to bicyclo[5.3.0]decanones and to bicyclo[6.3.0]undecanones

C. W. Ellwood, Gerald Pattenden · Tetrahedron Letters · 1991 · 68 citations

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Facile radical decarboxylative alkylation of heteroaromatic bases using carboxylic acids and trivalent iodine compounds

Hideo Togo, Masahiko Aoki, Masataka Yokoyama · Tetrahedron Letters · 1991 · 65 citations

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