Study on the reaction of the anionic copper selenolate complex [Me₄N]₂[Cu₄(SePh)₆] with CS₂ in solvents; the crystal structure of a polymeric complex [CuS₂COMe]_n(I)

Abstract

The anionic copper selenolate complex [Me 4 N] 2 [Cu 4 (SePh) 6 ] reacted with CS 2 in solvents CH 3 CN/CH 3 OH or DMF/CH 3 OH producing an uncharged two-dimensional layer polymeric complex [Cu(S 2 COMe)] n (I) and a mononuclear complex [Cu(S 2 CNMe 2 ) 2 ] (II), respectively. The crystal structure of (I) is reported.