Concepedia

Synthesis of di-µ-oxo manganese(<scp>III</scp>/<scp>IV</scp>) complexes as functional models of L. Plantarum pseudo-catalase: influence of electronic and steric factors; catalysis and kinetics of hydrogen peroxide disproportionation

Michel Delroisse, Alain Rabion, Françoise Chardac, David Tétard, Jean Baptiste Verlhac, Laurent Fraisse, Jean-Louis Séris

Journal of the Chemical Society Chemical Communications · 1995 · 24 citations · 20 references

DOI

Concepts

Abstract

Di-µ-oxo dimanganese(III/IV) complexes are efficient catalysts for H2O2 disproportionation in neutral aqueous medium; the activity can be correlated to the electron density on the metal and the accessibility of the catalytic site.

References

20

Reversible reaction of dioxygen (and carbon monoxide) with a copper(I) complex. X-ray structures of relevant mononuclear Cu(I) precursor adducts and the trans-(.mu.-1,2-peroxo)dicopper(II) product

Zoltán Tyeklár, Richard R. Jacobson, Ning Wei et al. · Journal of the American Chemical Society · 1993 · 482 citations

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A role for manganese in oxygen evolution in photosynthesis

Kenneth Sauer · Accounts of Chemical Research · 1980 · 161 citations · Full text

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Quadridentate Chelate Compounds. II<sup>1</sup>

Harold A. Goodwin, Francis Lions · Journal of the American Chemical Society · 1960 · 150 citations

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Pseudocatalase from Lactobacillus plantarum: evidence for a homopentameric structure containing two atoms of manganese per subunit

Wayne F. Beyer, Irwin Fridovich · Biochemistry · 1985 · 138 citations

, , +12

Dimanganese(II) complexes of a septadentate ligand. Functional analogs of the manganese pseudocatalase

Pradeep Mathur, Michael W. Crowder, G. Charles Dismukes · Journal of the American Chemical Society · 1987 · 129 citations

, , +12