Journal de Physique II · 1994 · 85 citations · 3 references
Natural SciencesMaterials SciencePhysicsCondensed Matter PhysicsPhase TransformationsPhysical ChemistryColloidal DispersionsNanoparticle DispersionsPhase DiagramsPhase EquilibriaPhase TransitionsThermodynamics Of Phase EquilibriaOrder TransitionsParticle DispersionPhase Dispersion
Latex polyballs are suspended in an isotropic micellar solution which exhibits a nematic phase at low temperatures. At the transition, we observe that the particles are either retained or expelled from the structured phase depending on their size. A mean field theory with two coupled order parameters is proposed to account for this behavior at the transition. The experimental and theoretical phase diagrams are in qualitative agreement.
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