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Enantioselective Inclusion Complexation ofN-Nitrosopiperidines by Steroidal Bile Acids
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1999
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Asymmetric CatalysisBioorganic ChemistryEngineeringBiochemistrySteroidal Bile AcidsHindered RotationNatural SciencesReactive Nitrogen SpecieCrystal Host MatricesSynthetic ChemistryStereoselective SynthesisN-n BondCrystallographyNitrosative StressEnantioselective SynthesisBiomolecular Engineering
N-nitrosamines, whose chirality is solely due to hindered rotation about the N-N bond, are enantioselectively enclathrated by the crystal host matrices of cholic or deoxycholic acid, as evidenced by X-ray crystallography (see structure in picture) and CD spectra.