Concepedia

First EPR characterisation of the structures and reactivities of α- and β-boryl radicals derived from boronic esters

Andrew J. McCarroll, John C. Walton, Andrew J. McCarroll, Roger Nziengui, Bertrand Carboni

Chemical Communications · 1997 · 15 citations · 14 references

DOI

Concepts

Abstract

The first EPR observations of carbon-centred radicals with α- and β-boronic ester substitutents indicated moderate thermodynamic stabilisation for the former whereas the latter had an inclination towards β-scission.

References

14

Electron spin resonance studies of conformations and hindered internal rotation in transient free radicals

Paul J. Krusic, Paul Meakin, J. P. Jesson · The Journal of Physical Chemistry · 1971 · 148 citations

, , +14

Radical reactions in organoboron chemistry II — Inter- and intramolecular addition of carbon centered radicals to alkenylboranes

Nathalie Guennouni, Frédéric Lhermitte, Sylvain Cochard et al. · Tetrahedron · 1995 · 81 citations

, , +6

Electron spin resonance studies of homolytic substitution reactions. Organoboron, -aluminum, and -gallium compounds

Paul J. Krusic, Jay K. Kochi · Journal of the American Chemical Society · 1969 · 67 citations

, , +12

(Alkoxyalkyl)boronic Ester Intermediates for Asymmetric Synthesis

Donald S. Matteson, R. Soundararajan, O. C. HO et al. · Organometallics · 1996 · 51 citations

, , +14

Preparation and properties of some pentafluorophenyl group IV compounds

A.J. Oliver, W. A. G. GRAHAM · Journal of Organometallic Chemistry · 1969 · 49 citations

, , +1