Concepedia

X-Ray Evidence for Molecular Dimerization at Neutral-Ionic Transition in TTF-Chloranil

S. Kagoshima, Yasuyuki Kanai, Masato Tani, Yoshinori Tokura, Takao Kōda

Molecular crystals and liquid crystals · 1985 · 32 citations · 10 references

DOI

Concepts

Abstract

Abstract An abrupt change of some Bragg reflections occurs near the neutral-ionic transition temperature(TN-I) in TTF-chloranil. We performed intensity analyses of (3 k l) Bragg refrections below TN-I and found that donor (TTF+:D) and acceptor (chloranil−:A) molecules form D-A dimers below TN-I

References

10

Discovery of a Neutral-to-Ionic Phase Transition in Organic Materials

J. B. Torrance, J. E. Vazquez, J. J. Mayerle et al. · Physical Review Letters · 1981 · 656 citations

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Anomalous Nature of Neutral-to-Ionic Phase Transition in Tetrathiafulvalene-Chloranil

J. B. Torrance, Alberto Girlando, J. J. Mayerle et al. · Physical Review Letters · 1981 · 398 citations

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Vibrational spectroscopy of mixed stack organic semiconductors: Neutral and ionic phases of tetrathiafulvalene–chloranil (TTF–CA) charge transfer complex

Alberto Girlando, Franca Marzola, C. Pecile et al. · The Journal of Chemical Physics · 1983 · 211 citations

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Mixed-stack complexes of tetrathiafulvalene. The structures of the charge-transfer complexes of TTF with chloranil and fluoranil

J. J. Mayerle, J. B. Torrance, J. I. Crowley · Acta Crystallographica Section B · 1979 · 123 citations

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Behavior of charge-transfer absorption upon passing through the neutral-ionic phase transition

Claus S. Jacobsen, J. B. Torrance · The Journal of Chemical Physics · 1983 · 119 citations · Full text

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