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Stereocontrolled synthesis of C-glycosides by reaction of organocuprates with protected 1,2-anhydro sugars, and their transformation into 2-deoxy-C-glycosides
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1989
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Asymmetric CatalysisEngineeringBiochemistryAffords 2-Deoxy-c-glycosidesNatural SciencesGlycobiologyProtected 1,2-Anhydro SugarsOrganic ChemistryPolysaccharideHigh YieldStereoselective SynthesisChemistryStereocontrolled SynthesisCarbohydrate-protein InteractionBiomolecular EngineeringGlycosylation
The reaction of protected 1,2-anhydro sugars with organocuprates provides a new stereocontrolled synthesis of C-glycosides, the deoxygenation of which affords 2-deoxy-C-glycosides in high yield.