Concepedia

A Facile Route to Convert Acetylacetone into Other β-Diketones with Acyl Chlorides Promoted by Samarium Triiodide

Yongmin Zhang, Taokai Ying, Pin Lü

Synthetic Communications · 1996 · 15 citations · 10 references

DOI

Concepts

Abstract

Abstract Reaction of acetylacetone with acyl chlorides in the presence of SmI3 gave β-diketones RCOCH2COCH3 (I) or RCOCH2COR (II) in good yields under mild and neutral conditions.

References

10

Tetrahedron report number 213

Henri B. Kagan, Jean‐Louis Namy · Tetrahedron · 1986 · 493 citations

, , +1

Lanthanoid Triflate Catalyzed Conjugate Addition of Amines to α, β-Unsaturated Esters. A Facile Route to Optically Active β-Lactam

Seijiro Matsubara, Masahito Yoshioka, Kiitirô Utimoto · Chemistry Letters · 1994 · 97 citations

, , +7

Reduction using samarium diiodide-base system

Yasuko Kamochi, T. KUDO · Tetrahedron Letters · 1991 · 46 citations

, , +2

Catalytic Aldol Reaction with Sm(HMDS)3 and Its Application for the Introduction of a Carbon-Carbon Triple Bond at C-13 in Prostaglandin Synthesis

Hiroaki Sasai, Shigeru Arai, Masakatsu Shibasaki · The Journal of Organic Chemistry · 1994 · 42 citations

, , +10

Iron(II) catalyzed persulfate oxidation of alkenes to vicinal diacetates

William E. Fristad, J. R. Peterson · Tetrahedron Letters · 1983 · 35 citations

, , +8