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Allyl silanes in organic synthesis: some reactions of 3-trimethylsilylcyclohex-4-ene-1,2-dicarboxylic acid and its derivatives
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1976
Year
3-Trimethylsilylcyclohex-4-ene-1,2-dicarboxylic AcidCross-coupling ReactionEnantioselective SynthesisEngineeringOrganic ChemistryDouble BondOrganometallic CatalysisStereoselective SynthesisChemistryPeracetic AcidAllyl SilanesBiomolecular Engineering
The allyl silanes (1), (2), and (3) react with acid, peracetic acid, and phenylsulphenyl tetrafluoroborate, respectively, to give electrophilic substitution products with loss of the trimethylsilyl group and a shift of the double bond.