Publication | Closed Access
Reaction of 2-(Phenylazo)aniline with Na<sub>2</sub>PdCl<sub>4</sub>: Formation of a 2-(Phenylazo)imino Complex of Bivalent Palladium
47
Citations
23
References
2001
Year
Long C−c DistancesEngineeringChemistryBivalent PalladiumInorganic CompoundChemical EngineeringStructure ElucidationOrganometallic CatalysisInorganic ChemistryBiochemistryChemical BondMolecular ChemistryStructural StudiesSupramolecular ChemistryInorganic SynthesisAmino ProtonsNatural SciencesImino ComplexCoordination ComplexHydrogen Bond
2-(Phenylazo)aniline, H2L (H stands for amino protons), binds to bivalent palladium in a bidentate fashion (N,N) as HL-. Structural studies show distortion in the phenyl ring adjacent to the chelate ring with two short and four long C−C distances.
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