Isoreticular Homochiral Porous Metal−Organic Structures with Tunable Pore Sizes

Abstract

Chiral-layered building motifs of zinc(II) camphorate are linked through linear N-donor ligands, forming series of three-dimensional isoreticular porous homochiral frameworks. The lengths of these linear ligands control the pore sizes and free accessible volumes of the homochiral metal-organic structures.