Concepedia

SYNTHESIS OF SILYL ENOL ETHER. REACTION OF SILYLENE WITH CARBONYL COMPOUNDS

Wataru Andō, Masayuki Ikeno

Chemistry Letters · 1978 · 23 citations · 4 references

DOI

Concepts

Abstract

Abstract Under neutral and mild conditions, silyl enol ethers are synthesized in good yields by the reactions of ketones or aldehydes with dimethylsilylene, which generated by the photolysis of dodecamethylcyclohexasilane.

References

4

Chemistry of carbanions. XVIII. Preparation of trimethylsilyl enol ethers

Herbert O. House, Leonard J. Czuba, Martin Gall et al. · The Journal of Organic Chemistry · 1969 · 754 citations

, , +4

Silylations with Bis(trimethylsilyl)acetamide, a Highly Reactive Silyl Donor

Johann F. Klebe, Herman Finkbeiner, Dwain M. White · Journal of the American Chemical Society · 1966 · 373 citations

, , +8

Photolysis of dodecamethylcyclohexasilane generation of dimethylsilylene and some of its insertion reactions

Mitsuo Ishikawa, Makoto Kumada · Journal of Organometallic Chemistry · 1972 · 114 citations

, , +10

An Extension of and the Reversibility of the Silylamine-Amine Exchange Reaction<sup>1,2</sup>

Ralph J. Fessenden, David Crowe · The Journal of Organic Chemistry · 1961 · 45 citations

, , +6