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Indium(III) Chloride−Sodium Borohydride System: A Convenient Radical Reagent for an Alternative to Tributyltin Hydride System
124
Citations
2
References
2002
Year
EngineeringOrganic ChemistryCatalytic PerformanceChemistryInorganic CompoundChemical EngineeringIndium HydrideOrganometallic CatalysisInorganic ChemistryCross-coupling ReactionChloride−sodium Borohydride SystemCatalysisTributyltin Hydride SystemPharmacologyNatural Product SynthesisCatalytic SynthesisAlkene MetathesisConvenient Radical ReagentIntramolecular CyclizationSynthetic Chemistry
The indium hydride generated from NaBH4 and InCl3, is a promising candidate of alternative to Bu3SnH. In particular, the catalytic performance of InCl3 in the dehalogenation of alkyl and aryl halides, intramolecular cyclization and intermolecular coupling reaction are noteworthy.
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