Indium(III) Chloride−Sodium Borohydride System:  A Convenient Radical Reagent for an Alternative to Tributyltin Hydride System

Katsuyuki Inoue, Akemi Sawada, Ikuya Shibata, Akio Baba

Journal of the American Chemical Society · 2002 · 124 citations · 2 references

Concepts

Abstract

The indium hydride generated from NaBH4 and InCl3, is a promising candidate of alternative to Bu3SnH. In particular, the catalytic performance of InCl3 in the dehalogenation of alkyl and aryl halides, intramolecular cyclization and intermolecular coupling reaction are noteworthy.

References

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