Negative coupling during oscillatory pattern formation on a ring electrode

Abstract

Pattern formation during the oscillatory electrodissolution of Co was studied using a Co ring electrode with a small reference electrode at a short distance in the center of the ring. Traveling pulses as well as source points (one-dimensional target patterns) were observed. These findings could be reproduced using a reaction-migration equation (RME) the coupling function of which was derived for the particular geometry from basic potential theory and was found to become negative for increasing distance. During pattern formation (i.e., for inhomogeneous potential distribution) the potential drop across the double layer could actually exceed the external applied voltage giving direct evidence for negative coupling.