Organic Letters · 2006 · 233 citations · 9 references
Natural SciencesChemistryCatalysisOrganic ChemistryOrganometallic ChemistryCatalyst DesignCatalyst PreparationCatalytic MaterialsCatalytic MechanismsOrganometallic SynthesisRedox CatalysisAlcohol OxidationAtom Transfer CatalysisHydrogenationHydrogenation CatalysisOrganoiridium ChemistryTransfer HydrogenationTransition Metal-catalyzed Synthesis
[reaction: see text] The iridium catalyst [Ir(Cp*)Cl2]2 is effective for the rearrangement of oximes to furnish amides. The reaction has been combined with catalytic transfer hydrogenation between an alcohol and alkene to allow the conversion of alcohols into amides in a one-pot process.
9
Asymmetric Transfer Hydrogenation of Imines
Nobuyuki Uematsu, Akio Fujii, Shohei Hashiguchi et al. · Journal of the American Chemical Society · 1996 · 816 citations
N-Alkylation of amines with alcohols catalyzed by a Cp*Ir complex
Ken‐ichi Fujita, Zhenzi Li, Naohiro Ozeki et al. · Tetrahedron Letters · 2003 · 276 citations