Concepedia

Highly enantioselective epoxidation of unfunctionalized olefins catalyzed by a novel recyclable chiral poly-salen–Mn(iii) complex

Yuming Song, Xiaoquan Yao, Huilin Chen, Guizhi Pan, Xinquan Hu, Zhuo Zheng

Journal of the Chemical Society Perkin Transactions 1 · 2002 · 25 citations · 7 references

DOI

Concepts

Abstract

A new soluble recyclable poly-salen–Mn(III) complex has been synthesized and found to give high enantioselectivities (up to 97% ee) for the asymmetric epoxidation of unfunctionalized olefins.

References

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