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NIH shift in haemin–iodosylbenzene-mediated hydroxylations
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1981
Year
Inorganic ChemistryEngineeringBiochemistryReactive Nitrogen SpecieNatural SciencesNitrosative StressPhenolic ProductsMarked Nih ShiftOrganic ChemistryNih ShiftCatalysisRedox ChemistryChemistryDeoxygenationRedox BiologyAromatic Substrates
Iron(III) and manganese(III) porphyrins catalyse the oxygen transfer from iodosylbenzene to aromatic substrates to yield phenolic products; the resultant p-methoxyphenol or p-cresol exhibits a marked NIH shift.