SYNTHESES AND CHARACTERIZATION OF ALUMINIUM(III), IRON(III), AND COPPER(II) MONOBROMOACETATES AND THEIR COMPLEXES WITH ORGANIC BASES

Abstract

Bromoacetates of the compositions Al(OOCCH2Br)3, AlBr(OOCCH2Br)2, FeCl(OOCCH2Br)2, FeCl2(OOCCH2Br) and Cu(OOCCH2Br)2 and M(OOCCH2Br)3·B, M(OOCCH2Br)2·2B, MBr(OOCCH2Br)2·B, MCl(OOCCH2Br)2·2B, MCl2(OOCCH2Br)·B. (M═Al(III), Fe(III), Cu(II) and B ═ C5H5N, (C2H5)2NH, (C2H5)3N and NH2C6H4F have been synthesized and characterized on the basis of elemental analyses, infrared, reflectance, NMR spectral and magnetic susceptibility studies.