Publication | Closed Access
Instantaneous Deprotection of Tosylamides and Esters with SmI<sub>2</sub>/Amine/Water
186
Citations
35
References
2009
Year
Derivative (Chemistry)Instantaneous DeprotectionEngineeringBiochemistryNatural SciencesBiocatalysisTosyl AmidesFunctionalized SubstratesPeptide SynthesisOrganic ChemistryAnalytical ChemistryChromatographyEnzymatic ModificationChemical DerivativeInstantaneous CleavageBiomolecular Engineering
SmI(2)/amine/water mediates instantaneous cleavage of tosyl amides and tosyl esters. Highly hindered, sensitive and functionalized substrates were successfully deprotected in near quantitative yield.
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