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Spatially controlled photocycloaddition of a clay-intercalated stilbazolium cation
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1989
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Syn Head-to-tail DimerChemical EngineeringSupramolecular PhotochemistryEngineeringPhotochemistrySynthetic PhotochemistryPhotocatalysisOrganic ChemistryStilbazolium CationChemistryClay-intercalated Stilbazolium CationClay Interlayers
A stilbazolium cation included in clay interlayers undergoes an efficient and regioselective photocycloaddition to afford a syn head-to-tail dimer with suppression of the cis–trans isomerization.