Angewandte Chemie International Edition · 2001 · 64 citations · 20 references
Natural SciencesChemical EngineeringChemistryCatalysisElectrochemistryOrganic ChemistryAnode MaterialsCatalyst PreparationCatalyst RegenerationCatalytic MaterialsElectrochemical SynthesisRedox CatalysisAldehydesElectrocatalystsElectrochemical C - C Bond FormationElectrochemical RegenerationElectrochemical Synthesis Of CatalystsRegeneration Strategies
It seems almost paradoxical that reactive low-valent indium(I) species can be generated at the anode through reduction of indium(III) salts under electrochemical conditions (see scheme). The resulting indium(I) species are highly effective catalysts for the allylation of different aldehydes, ketones, and esters on a preparative scale.
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Synthetic Organoindium Chemistry: What Makes Indium so Appealing?
Pedro Cintas · Synlett · 1995 · 291 citations