Publication | Closed Access
Oxidative Carbonylation of Alkynyltungsten Compounds via Protonation with Triflic Acid
11
Citations
6
References
1998
Year
Chemical EngineeringCross-coupling ReactionEngineeringAlkene MetathesisElectrosynthesisOrganic ChemistryOrganometallic CatalysisCatalysisChemistryAlkynyltungsten CompoundsSeveral AlkynyltungstenSynthetic ChemistryMol EquivOxidative Carbonylation
Treatment of several alkynyltungsten(II) compounds with 4.0 mol equiv of CF3SO3H led to oxidative carbonylation to yield acyltungsten(IV) compounds; this reaction can be applied to syntheses of indanones and unsaturated carbonyl compounds.
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