Concepedia

Nickel Ethylene Polymerization Catalysts Based on Phosphorus Ligands

Neil A. Cooley, Simon M. Green, Duncan F. Wass, K. Heslop, A.G. Orpen, Paul G. Pringle

Organometallics · 2001 · 134 citations · 5 references

DOI

Concepts

Abstract

Nickel(II) complexes of ligands of the type Ar 2 PN(Me)PAr 2 (Ar = ortho -substituted phenyl group) are highly active and poison-tolerant catalysts for the polymerization of ethylene.

References

5

New Pd(II)- and Ni(II)-Based Catalysts for Polymerization of Ethylene and .alpha.-Olefins

Lynda K. Johnson, Christopher M. Killian, Maurice Brookhart · Journal of the American Chemical Society · 1995 · 2.7K citations

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Neutral, Single-Component Nickel (II) Polyolefin Catalysts That Tolerate Heteroatoms

Todd R. Younkin, Eric F. Connor, Jason I. Henderson et al. · Science · 2000 · 1.1K citations

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Synthesis of Branched Polyethylene Using (α-Diimine)nickel(II) Catalysts:  Influence of Temperature, Ethylene Pressure, and Ligand Structure on Polymer Properties

Derek P. Gates, Steven A. Svejda, Enrique Oñate et al. · Macromolecules · 2000 · 717 citations

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Novel Coordination of (Benzoylmethylene)triphenylphosphorane in a Nickel Oligomerization Catalyst

Wilhelm Keim, Frank H. Kowaldt, Richard Goddard et al. · Angewandte Chemie International Edition in English · 1978 · 420 citations

, , +13

Coordination polymerization of ethylene in water by Pd(ii) and Ni(ii) catalysts

Anke Held, Florian M. Bauers, Stefan Mecking · Chemical Communications · 2000 · 129 citations · Full text

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