Surface driven effects on magnetic properties of antiferromagnetic LaFeO3 nanocrystalline ferrite

Abstract

LaFeO3 nanocrystalline ferrites were synthesized through sol-gel method in different size distributions and the effect of finite size on magnetic properties is investigated. Results of magnetization and Mössbauer measurements show that superparamagnetism and weak ferromagnetic behavior in some of the size distributions. The origin of the superparamagnetism is from fine particles similar to ferromagnetic single domains and the weak ferromagnetism comes from surface spin disorder caused by Dzyaloshinskii-Moriya interaction. The magnetic ground state of LaFeO3 nanoparticles differs from that of bulk, and the ground state is dictated by the finite size effect because density of states depends on the dimensionality of the sample.