THE TRUEX PROCESS - A PROCESS FOR THE EXTRACTION OF THE TKANSURANIC ELEMENTS EROM NITRIC AC In WASTES UTILIZING MODIFIED PUREX SOLVENT*

TLDR

A major feature of the process is that it is readily adaptable for waste processing in existing fuel reprocessing facilities. A generic transuranic element extraction/recovery process was developed using octyl(phenyl)-N,N‑diisobutylcarbamoylmetylphosphine oxide dissolved in PUREX solvent (TBP in normal paraffluic hydrocarbon). The TRUEX process reduces TRU concentration by many orders of magnitude in waste solutions with varied nitric acid, salt, and fission product concentrations. Work performed under the auspices of the Office of Basic Energy Sciences, Division of Chemical Sciences, U.S.

Abstract

ABSTRACT A generic transurantc (TRU) element extraction/recovery process was developed based on the use of octyl(phenyl)-N,N-diiso-butylcarbamoylmetliylphosphine oxide, 0φD(iB)CMPO, dissolved in PUREX process solvent (tribntyl phosphate, TBP, in normal paraffluic hydrocarbon, NPH). The process (called TRUEX) is capable of reducing the TRU concentration by many orders of magnitude In waste solutions containing a wide range of nitric acid, salt, and fission product concentrations. A major feature of the process is that it is readily adaptable for waste processing in existing fuel reprocessing facilities. Notes *Work performed under the auspices of the Office of Basic Energy Sciences, Division of Chemical Sciences, U. S. Department of: Energy under contract number W-31-109-ENG-38. Additional informationNotes on contributorsGeorge F. Vandegrift Chemical. Technology Division.