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Polystyrene-block-poly(2-cinnamoylethyl methacrylate) Nanofibers—Preparation, Characterization, and Liquid Crystalline Properties
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1999
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EngineeringFiber SpinningNanostructured PolymerFiber ScienceChemistrySoft MatterPolymersPolymer MaterialLiquid Crystalline PhasesPolymer CompositesBiophysicsPolymer ChemistryMaterials ScienceCylindrical FibersDiblock CopolymerLiquid Crystalline PropertiesFiber ChemistryNanofiberFiber StructurePolymer SciencePolymer Characterization
Cylindrical fibers that are tens of micrometers long and ∼100 nm across are synthesized from a diblock copolymer (see figure). The determination of their persistence length and other size parameters in organic solvents by light-scattering has been heroic. The fibers form liquid crystalline phases in bromoform.