Ionothermal Synthesis of Unusual Choline‐Templated Cobalt Aluminophosphates

Abstract

Into the deep: A deep-eutectic solvent based on choline chloride and one of several carboxylic acids can be used to prepare cobalt aluminophosphate analogues of zeolites. One of the new materials contains unusual ring-opened double-four-ring units, in which a cobalt atom forms a terminal CoCl bond (see picture; Co cyan, Al gray, P purple, O red, Cl green). Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2007/z702239_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.